Ni60A添加对激光熔覆铁基涂层耐腐蚀性能的影响

    Effect of Ni60A Addition on Corrosion Resistance of Laser-cladded Fe-based Coatings

    • 摘要: 激光熔覆铁基涂层因制备效率高、成本低、涂层与基体结合强度高等优势而受到广泛关注。为提升涂层的耐腐蚀性能,以Fe基预合金粉末为基体,添加Ni60A粉末,采用激光熔覆工艺制备铁基复合涂层。结果表明,涂层内部存在分布不均匀的富铬棒状树枝状晶;随着Ni60A含量增加,涂层腐蚀电位先正向偏移后负偏移,腐蚀电流密度则呈相反趋势变化,表明涂层的耐腐蚀性能先升高后下降。在几种涂层体系中,4wt% Ni60A的涂层腐蚀电位为-0.228 V,腐蚀电流密度为9.6×10-7 A·cm-2,耐腐蚀性能优于其余Ni60A添加涂层,具有最优耐蚀性。为揭示涂层的腐蚀机理,进行了电化学阻抗谱和X射线光电子能谱测试,分析了不同Ni60A添加含量对涂层耐蚀性能的影响规律。

       

      Abstract: Laser-cladded Fe-based coatings possess the advantages of high preparation efficiency, low cost and high bonding strength between the coating and the base materials, which has attracted extensive attention focusing on the improvement of the corrosion resistance. Ni60A alloyed Fe-based composite coatings were obtained using laser cladding process. The results show that the microstructure of the coatings are found to consist of unevenly dispersed rod-like Cr-rich dendritic crystal grains. As the Ni60A content increases, the corrosion potential shifts positively first and then negatively, while the corrosion current density exhibits an opposite trend, which indicates that the corrosion resistance of the coatings increases initially and then decreases. The 4wt%Ni60A coating has optimum corrosion resistance with a corrosion potential of -0.228 V and a corrosion current density of 9.6×10-7 A·cm-2 superior to other Ni60A-added coatings. The electrochemical impedance spectroscopy (EIS) and X-ray photoelectron spectroscopy (XPS) analysis were carried out to reveal the corrosion mechanism. The effects rule of Ni60A addition on the corrosion behavior of the coating were analyzed.

       

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