氮分压对ZrN涂层晶体取向和耐蚀性能的影响

    Effects of Nitrogen Partial Pressure on Crystal Orientation and Corrosion Resistance of ZrN Coatings

    • 摘要: 为提高海洋石油装备的耐蚀性能,采用多弧离子镀技术在304不锈钢衬底上制备不同氮分压ZrN涂层。采用扫描电子显微镜(SEM)、掠入射X射线衍射(GIXRD)对ZrN涂层的微观形貌和晶体结构进行分析;利用电化学测试方法,探讨了ZrN涂层晶体织构对于耐蚀性能的影响机制。结果表明,随着氮分压的升高,ZrN涂层的表面形貌无明显变化,截面均为致密柱状结构,但晶体取向由(111)逐渐演变为(200);具有(200)取向的涂层耐蚀性能最优,电容最低为7.62 μF·cm-2,保护效率达89.72%,这归因于(200)取向具有更高的钝化倾向和钝化膜稳定性。

       

      Abstract: In order to improve the corrosion resistance of offshore oil equipment, ZrN coatings with different nitrogen partial pressures were prepared on 304 stainless steel substrate by multi-arc ion plating. The microstructure and crystal structure of ZrN coating were analyzed by scanning electron microscope and X-ray diffraction. The influence mechanism of crystal texture of ZrN coating on corrosion resistance was discussed by electrochemical testing methods. The results show that with the increase of nitrogen partial pressure, there is no significant difference in the surface morphology of ZrN coatings. The cross sections are dense columnar structures, and the crystal orientation evolves from (111) to (200). The coating with (200) orientation has the best corrosion resistance, the lowest coating capacitance is 7.62 μF·cm-2, and the protection efficiency is as high as 89.72%, which is attributed to the higher passivation tendency and the stability of the passivation film.

       

    /

    返回文章
    返回