Cr功率对304不锈钢表面制备Cr/MoS2-DLC薄膜摩擦腐蚀性能的影响

    Effect of Cr Power on Tribological Properties and Corrosion Properties of Cr/MoS2-DLC Films Prepared on 304 Stainless Steel Surfaces

    • 摘要: 在恶劣海洋环境中,海洋工程设备面临巨大的磨损和腐蚀问题。然而,传统的单一类金刚石薄膜已无法满足该性能要求。为了改善该薄膜的性能,采用直流磁控溅射技术,在304不锈钢基体上沉积了Cr/MoS2-DLC薄膜,研究了Cr功率对该薄膜摩擦学性能与腐蚀性能的影响。通过扫描电子显微镜、能谱仪、X射线光电子能谱仪及拉曼光谱仪等多种手段对其进行微观结构与价态的表征;同时,利用纳米压痕仪与摩擦实验机对薄膜的力学性能与摩擦学性能进行了测试。结果表明,Cr/MoS2-DLC薄膜的表面组织结构致密且均匀分布、薄膜质量较好、无明显的裂纹及孔洞产生。在3种薄膜中,Cr功率为20 W的薄膜性能最佳,该薄膜的硬度及弹性回复率分别约为17.60 GPa、55.26%;在大气环境、去离子水及人工海水环境中的摩擦系数分别约为0.10、0.12和0.13;腐蚀电位与腐蚀电流密度约为0.0055 V、2.83×10-8 A/cm2,该薄膜表现出最佳的减摩与耐腐特性,对基体起到了良好的防护作用,有效改善了基体的摩擦学性能与腐蚀性能。

       

      Abstract: In the harsh Marine environment, Marine engineering equipment is faced with great wear and corrosion problems. However, the traditional single diamond-like carbon films(DLC) can not meet the performance requirements. In order to improve the performance of DLC films, Cr/MoS2-DLC films were deposited on 304 stainless steel substrates by DC magnetron sputtering technology. The effects of Cr power on the tribological propeties and corrosion properties of the composite films were studied. The microstructure and valence states were characterized by scanning electron microscope, energy spectrometer, X-ray photoelectron spectrometer and Raman spectrometer. Meanwhile, the mechanical properties and tribological properties of the films were tested by a nano-indentation instrument and friction tester. The results show that the surface microstructure of Cr/MoS2-DLC films are compact and evenly distributed, the quality of the films is good, and there are no obvious cracks and holes. Among the three films, the film with Cr power of 20 W has the best performance. The hardness and elastic recovery rates of the films is about 17.60 GPa and 55.26%, respectively. The friction coefficients in the atmospheric environment, deionized water and artificial seawater are about 0.10, 0.12 and 0.13, respectively. The corrosion potential and corrosion current density are about 0.0055 V and 2.83×10-8 A/cm2. It shows the best anti-friction and anti-corrosion properties, plays an excellent protective role for the matrix, and effectively improves the tribological properties and corrosion properties of the matrix.

       

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