稀土Ce变质ZK60变形镁合金的微观组织及其机制研究

    Study on Microstructure and Mechanism of Rare Earth Ce Modified ZK60 Wrought Magnesium Alloy

    • 摘要: 在ZK60变形镁合金基体中加入了不同质量分数的稀土元素Ce。借助金相、SEM、EDS、XRD研究稀土Ce变质ZK60变形镁合金微观组织演变,探讨变质机理。结果表明,当Ce从0%增加到0.9wt%时,合金晶粒尺寸逐渐减小,尺寸由88 μm减小到51 μm,抗拉强度由104 MPa增加到160 MPa,伸长率从6%增加到7%;当Ce增加到1.2wt%时,晶粒尺寸反而增大到61 μm,出现过变质现象;MgZn2可作为α-Mg的异质形核核心;Ce、Mg与Zn结合成Mg42Zn53Ce5化合物钉扎在晶界处,有利于减小晶粒尺寸。

       

      Abstract: Rare earth elements Ce with different mass fractions were added to the ZK60 wrought magnesium alloy matrix. The microstructure evolution of rare earth Ce modified ZK60 wrought magnesium alloy was studied by means of metallography, SEM, EDS and XRD, and the modification mechanism was discussed. The results show that when Ce is increased from 0%to 0.9wt%, the grain size of the alloy is gradually decreased, the size is decreased from 88 μm to 51 μm, the tensile strength is increased from 104 MPa to 160 MPa, and the elongation is increased from 6%to 7%.When Ce increases to 1.2wt%, the grain size increases to 61 μm instead, and the metamorphism occurs; MgZn2 can be used as the heterogeneous nucleation core of α-Mg; Ce, Mg and Zn combine to form Mg42Zn53Ce5 compound pinned at the grain boundary, which is beneficial to reduce the grain size.

       

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