微量Te对Cu-Cr-Zr合金组织及性能的影响

    Effects of Trace Te on Microstructure and Properties of Cu-Cr-Zr Alloy

    • 摘要: 采用SEM、EDS等微观表征以及显微硬度和导电性能检测手段,研究了Te含量对Cu-Cr-Zr-Te合金铸态组织及性能的影响。结果表明:随着Te含量的增加,铸态Cu-Cr-Zr-Te合金的硬度呈逐渐升高的的趋势,但导电性能基本趋于稳定状态,热锻处理后合金的硬度和导电率都有所上升。铸态Cu-Cr-Zr-Te合金中低含量Te与Zr结合力较强易形成CuZrTe化合物,提升Te含量倾向于形成CuCrTe化合物;合金经900℃/4h的保温、热锻处理后,CuCrTe化合物分解为富Te相和富Cr相造成基体中Te元素的贫化,导致元素Te与元素Cr的相对比例减小而形成CuZrTe化合物。

       

      Abstract: The influence of Te content on the as-cast structure and properties of Cu-Cr-Zr-Te alloy was studied by SEM, EDS and other micro-characterization and micro-hardness and electrical conductivity testing methods.The results show that with the increase of Te content, the hardness of the as-cast Cu-Cr-Zr-Te alloy gradually increases, but the electrical conductivity basically tends to a stable state.The hardness and electrical conductivity of the alloy increase after hot forging.In as-cast Cu-Cr-Zr-Te alloy, the low content of Te and Zr have a strong binding force, which is easy to form CuZrTe compounds. Increasing the content of Te tends to form CuCrTe compounds; after the alloy is heated at 900℃/4h and hot forging treatment, the CuCrTe compound decomposed into a Te-rich phase and a Cr-rich phase results in the depletion of Te element in the matrix, resulting in the decrease in the relative ratio of element Te and Cr to form CuZrTe compounds.

       

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