2A12铝合金的低压微弧氧化制备与性能研究

    Research on Preparation and Properties of 2A12 Aluminum Alloy by Low Pressure Microarc Oxidation

    • 摘要: 微弧氧化是一种优秀的表面处理手段,适用于铝、镁、钛等阀金属。但目前微弧氧化处理所需电能过高,生产成本高,不符合绿色发展理念,限制了其应用。实验采用微弧氧化双向脉冲电源,在Na2SiO3-KOH电解液体系中,在2A12铝合金表面制备微弧氧化膜。在电解液中加入添加剂NaF,采用分段升压手段,在较低电压下制备微弧氧化膜。通过扫描电镜(SEM)、X-射线衍射(XRD)、电子能谱分析(EDS)、电化学工作站等手段表征其耐蚀性。结果表明,加入NaF能够有效降低微弧氧化所需的电压,在正向电压为220 V时微弧氧化即可反应,膜层主要成分为Al、Si、O,相结构组成主要为α-Al2O3,并存在非晶态Al2O3;在升压段数为4、升压速率为10 V/min、NaF浓度为1g/L时耐蚀性较好。

       

      Abstract: Micro-arc oxidation, as an excellent surface treatment method, is suitable for aluminum, magnesium, titanium, and other valve metals. However, the current energy required for micro-arc oxidation treatment is too high. The high production cost does not conform to the concept of green development, which limits its application. A bidirectional pulse power was supplied for the MAO process.Micro-arc oxidation films were prepared on the surface of 2A12 aluminum alloy in Na2SiO3-KOH electrolyte system.Adding additive NaF in the electrolyte, the micro-arc oxidation film was prepared under low voltage using stepwise voltage boost. The corrosion resistance was investigated by scanning electron microscopy (SEM), X-ray diffraction (XRD), electron energy spectrum analysis (EDS) and electrochemical workstation. The results show that adding NaF can effectively reduce the voltage required of micro-arc oxidation, and the reaction can be achieved when the forward voltage is 220V. The main composition of the film is Al, Si and O, and the phase structure is mainly α-Al2O3 and amorphous Al2O3. The corrosion resistance is better when the number of pressure boost segments is 4, the rate of pressure boost is 10 V/min and the concentration of NaF is 1g/L.

       

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